Very nice cover! Just checked Jim Forte's Postal History Website to learn that Athol Depot, Mass., is a discontinued post office that was only in operation for a mere 24 years, from 1849-1873, which should make that postmark relatively scarce.
This type of cover was favoured by mostly women at the time and in the years following, they have been given the name amongst philatelists as "Ladies Envelopes". They are a specialty.
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