Buffer is added to the paper pulp during manufacturing to counter the use of low quality new or recycled wood pulp in the slurry. Even the paper used to print the stamps has buffer in it.
Like any buffer (for example taking a Tums or other antacid after eating a spicy meal), the buffer only neutralizes acids for a short period of time. It also allows seller of cheap paper to fool buyers into thinking that today's paper are 'acid free'. As the paper naturally ages, the buffers become consumed. (This is no different than adding buffers to a pool or hot tub, the buffers become exhausted once the pH drops.) When there is no longer any buffers to react to the natural pH drop and paper turns acidic and begins to tone (turn brown and brittle). Adding a buffer into paper is only a temporary situation, a better solution is to buy rag paper without wood pulp (more expensive).
More information on this here
https://stampsmarter.org/learning/H...sePaper.htmlDon