Welcome, The discoloration can occur when a stamp is exposed to sulphur, a common chemical element present in many substances. When exposed to it, the color of the stamp can be dramatically altered into a much different and/or darker color. As with your stamp, this is most often seen is an orange or yellow stamp that has turned brown-color.
This sulphurization can be reversed with hydrogen peroxide. Don
Unfortunately, not an error. Actually, it's a defective stamp. Sulfur ions in the atmosphere are reacting with the orange pigment, turning it brown. A soak in 3% hydrogen peroxide solution for a minute or two, followed by a water rinse will reverse the effect.
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