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The Importance Of Glassine Envelopes?

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Pillar Of The Community
USA
9748 Posts
Posted 07/26/2012   10:22 pm  Show Profile Bookmark this reply Add philb to your friends list  Get a Link to this Reply
Its great that we have a lot of people of the site with a lot of related experience and information...with glassines going for 3,4 and 5 cents apiece..you would like to think they are acid free !!
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APS 070059 Life Member International Society of Guatemala Collectors I.S.G.C. #853
Bedrock Of The Community
United States
12128 Posts
Posted 07/27/2012   12:49 am  Show Profile Bookmark this reply Add wt1 to your friends list  Get a Link to this Reply
The following evaluation is from the Northeast Document Conservation Center, with particular focus on paper materials and photographs. Although stamps are not part of this specific evaluation, I think it provides a good summary of what to look out for in terms of use of papers said to be "acid-free" and/or use of glassine envelopes:


Quote:
The term acid-free is widely used to refer to archival-quality paper materials constructed of either neutral or buffered paper. A more precise distinction should be made between the two. Neutral enclosures, constructed of paper in the neutral pH range (6.5–7.5), do not contain acids that will damage photos stored in them, but have a limited capacity to neutralize acids from the environment or from paper deterioration. Buffered paper enclosures (pH 7.5–9.5) contain an alkaline material (such as calcium carbonate) that neutralizes acids as they form. In the past, conservators have recommended the use of neutral paper enclosures for storage of color images, cyanotypes, and albumen prints. It was believed that these processes were sensitive to the alkalinity in buffered papers. Recent research has indicated that buffered storage enclosures are not detrimental to photographs. Therefore whether paper is neutral or buffered is not a major criterion for choosing an enclosure.

Labels such as acid-free do not guarantee that a material is safe when used with photographs. Even archival papers may be harmful to the photographic image. The only way to be certain of the inertness of the paper is to have materials undergo the Photographic Activity Test (PAT) as specified in ISO 14523: 1999.2 The PAT has two components: a test to detect image fading resulting from harmful chemicals in enclosures; and a test to detect staining reactions between enclosures and gelatin. Consumers should contact suppliers of archival materials to see if their products comply with ISO 14523: 1999, and have passed the Photographic Activity Test.

When PAT test results are not available, purchase materials from suppliers familiar with the special needs of photographs, and choose enclosures that are lignin-free, 100% rag, and not highly colored. Glassine enclosures are not recommended. Glassine paper is made with short, brittle wood pulp fibers, which are prone to rapid decay. Often in the pulp are additives which increase the flexibility and translucency of the paper. Therefore, glassine has three sources of potential harm to photographs: possible impurities from wood pulp, possible harmful additions, and deteriorating paper fiber.


For more reading on the subject, you can check it out at this link:

http://www.nedcc.org/resources/leaf...closures.php
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Edited by wt1 - 07/27/2012 12:52 am
Valued Member
United States
16 Posts
Posted 07/27/2012   10:25 am  Show Profile Bookmark this reply Add polo_sal to your friends list  Get a Link to this Reply
Thanks everyone, that is some good stuff and stuff I would have never known. So here is what I gathered then would be a good rule of thumb for me.
1. Current stamps considering that the value would never be all that much, plastic bags would do okay.
2. Glassine that are acid free would be best for older stamps that I want to store away.
3. Stock books for all other stamps that I would like to be able to perserve for a longer period of time.

I think that is a gret start!
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Pillar Of The Community
Australia
578 Posts
Posted 06/24/2019   03:46 am  Show Profile Bookmark this reply Add Plateflaw to your friends list  Get a Link to this Reply
Westvaco disappeared as a company some years ago. Are any of its successor entities still manufacturing glassine envelopes? What Westvaco envelopes out there for sale by stockists appears to be old inventory.
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Pillar Of The Community
United States
8397 Posts
Posted 06/24/2019   08:29 am  Show Profile Bookmark this reply Add floortrader to your friends list  Get a Link to this Reply
I agree with NCBUCKEYE, I also have had stamps in glassines from the late 1960's and there is no effect on the stamps and the glassines have not yellowed or turn brown .This is both for Chicago and Florida climates .
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Pillar Of The Community
Canada
1462 Posts
Posted 06/24/2019   09:29 am  Show Profile Check gmot's eBay Listings Bookmark this reply Add gmot to your friends list  Get a Link to this Reply
Recently went through some stamps that had been in glassines since the early 1950s, and although the glassines had gone brownish, the stamps were fine. In any case, got rid of all the old envelopes and put into new, as could no longer easily see the stamps inside, along with some ancient glassine interleaving that had turned into a lovely tobacco brown colour...
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Rest in Peace
United States
4052 Posts
Posted 06/24/2019   5:37 pm  Show Profile Bookmark this reply Add ikeyPikey to your friends list  Get a Link to this Reply

Quote:
... the glassines had gone brownish, the stamps were fine ...


As this is both my experience, as well as that of others, with stamps as well as covers, may I ask a stupid question?

Q/ Could the glassine envelopes be acting as a sink for sulfur dioxide, et al, thus sparing their contents?

Cheers,

/s/ ikeyPikey (who takes note that of the authoritative posts above, to the effect that shorter fibers in glassine are more reactive)
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Edited by ikeyPikey - 06/24/2019 5:39 pm
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12330 Posts
Posted 06/24/2019   6:07 pm  Show Profile Bookmark this reply Add 51studebaker to your friends list  Get a Link to this Reply
No one in this thread has any idea if glassines are truly archival. And anecdotal evidence like 'I had some and they turned brown' or 'I had some and they are fine after 50 years' is virtually worthless.

Glassines are a price sensitive item, no one buys 3 or 4 at a time and no one collects them. There is no standard for making them. There is no regulatory oversight during manufacturing of glassines, there is no after market testing. Glassine manufacturers do not perform accelerated aging tests on their products.

What we do know is that there is plenty of evidence that older glassine can and will deteriorate and become acidic. I would agree that environmental conditions an important factor.
I would also agree that most of them are fine for a number of few years IF the proper environmental conditions are maintained.

The problem with glassines, acid free paper purchased at Staples, and preprinted album pages from major manufacturers is that this all marketing hype with no evidence based research or data to back any of it up.
If ANY of these manufacturers had invested the time and money into proper testing they would most surely be touting it in their advertising.

But it is far cheaper to throw a handful of buffer (bicarbonate) into the paper slurry, print 'acid free' on the label, and blame any field reports of acidification on poor environmental conditions.

And while some of us might be careful about how we store the material we have, we have no idea what will happened to it after it passes from our procession.
Don
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Posted 06/24/2019   6:17 pm  Show Profile Bookmark this reply Add 51studebaker to your friends list  Get a Link to this Reply

Quote:
Could the glassine envelopes be acting as a sink for sulfur dioxide, et al, thus sparing their contents?


Enclosing paper in anything is a double edge sword. The enclosure can keep bad atmospheric things away but they can also encapsulate bad things inside.

My opinion is that concentrating on maintaining the proper environment is paramount and to not trust or assume that any of the marketing hype is legitimate. The day that any of these manufacturer publishes real specifications and test data I will change my opinion.
Don
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Pillar Of The Community
Canada
1462 Posts
Posted 06/24/2019   7:19 pm  Show Profile Check gmot's eBay Listings Bookmark this reply Add gmot to your friends list  Get a Link to this Reply
I think we'll be stuck with anecdotal evidence for awhile, but I am a little surprised someone like Palo or Lighthouse hasn't done some proper testing of their products - you would think it could be a selling point to the high-end market?

Anecdotally again in my case, the stamps in glassines had been stored in a "good" environment without excessive heat, humidity or sunlight - for roughly 65 years. I'm sure if they'd been sitting in a damp basement for a significant period of that time, it'd be much sadder story, no matter whether in glassines, 102 cards or albums.
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Posted 06/24/2019   7:43 pm  Show Profile Bookmark this reply Add 51studebaker to your friends list  Get a Link to this Reply
I concur, in the current environment where self printing album pages are eroding market share every year, legacy publishers could have achieved marketplace separation. But it would have meant charging a LOT more than they do now and frankly I am not sure that most collectors would be bothered; they simply would go buy cheap 'acid free' paper at the local big box store and think themselves wise for saving so much money.
None of the philatelic publishers make their own paper; they simply buy it from a paper supplier who makes claims about how it was made. If any of the philatelic publishers test anything then they are certainly not saying a word about the results. Heck, it is hard to even find much anything about their album pages, we are lucky just to get a screen shot of a few pages.
Don
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Pillar Of The Community
Australia
578 Posts
Posted 06/24/2019   8:13 pm  Show Profile Bookmark this reply Add Plateflaw to your friends list  Get a Link to this Reply
Here are some experts... Society of American Archivists


https://www2.archivists.org/glossar...s/g/glassine



Quote:
Glassine is often used to make envelopes to store photographic negatives. Its hygroscopic properties make it inappropriate for archival use.



"Hygroscopic" is a characteristic or property whereby the subject absorbs moisture from the air.

Glassine absorbs moisture.
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Posted 06/24/2019   8:19 pm  Show Profile Bookmark this reply Add 51studebaker to your friends list  Get a Link to this Reply
All paper is hygroscopic, it is basically a sponge.

But even more difficult is finding much anything online regarding paper accelerated aging tests. Last time I looked (a few months ago) a could only find a few white papers that were all a number of years old. I found it hard to even find info on how they do accelerated aging testing on paper.
Don
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United States
4052 Posts
Posted 06/24/2019   8:34 pm  Show Profile Bookmark this reply Add ikeyPikey to your friends list  Get a Link to this Reply

Quote:
... Glassine absorbs moisture ...


Which leaves us innocent of whether/not this is a good thing.

If glassine absorbs water vapor (or anything else) more readily than stamps, that might very well be the good news.

As Don points out, controlling the environment (including the humidity) is your best first line of defense.

Cheers,

/s/ ikeyPikey (who notes that 'anecdotal' and 'reality' both have four syllables)
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Edited by ikeyPikey - 06/24/2019 8:37 pm
Pillar Of The Community
United States
2830 Posts
Posted 06/24/2019   11:44 pm  Show Profile Bookmark this reply Add shermae to your friends list  Get a Link to this Reply
102 cards have been mentioned within this thread as an appropriate storage option. My objection to 102 cards is that the adhesive used on 3 sides to attached the foil to the paper degrades over time. I have seen any number of 102 cards where the stamps have lodged into this degrading adhesive. I have no idea is this is a terminal situation or if it may be detrimental to the stamps over time. I always return such lots intact for a refund as I don't wish to find out.

Stamps + adhesive = ummm, no.

Additionally, how many of you have seen the adhesive on the bottom of 102-type cards fail completely, allowing the stamps to fall through the bottom of the card? It may not damage the stamps, but they certainly could become damaged when falling out.
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