Thank you for all your patience with me as I work through these questions...
My mother had this catalogued as SC #41 (issued 1883). It is not a stamp, though. Very stiff, imperf, writing on the back, etc.

Still on the very steep learning curve, so my questions are:
1) Am I right that this is from a postcard / some kind of postal stationary?
2) Does it have any significance? (ie, is it worth keeping?)
Much appreciation for any information someone might be willing and able to share. :)