I have done kind of a cursory look through and sort of an accumulation I
inherited. I have cataloged about 5000 stamps from the Deutsches Reich, BRD and DDR as well as a few territories and German states so far. I have at least that much more left that I haven't looked at. I also have several thousand from US, other European Countries, South America, Japan, China, and Africa as well as few from the middle east, India, and Pakistan.
Cataloged might be a strong term. I tried to sort them by year and series, although I am finding that for some series' years are tricky, esp. when you can't see the watermarks. I have been trying to note obvious errors listed in Michel specialized, but I am still trying to figure out types of glue, paper, and ink. I am also starting to sort based on watermarks. I have found about 250 Pieck Stamps from 1950 - 1953 and a few from 1957 - 1960. I have 400+ Portrait Types of the Russian Occupation. I am pretty sure 150 or so are from 1948 and 100 or so are from 1952/53. The rest are on cover material. I hesitate to say I know anything for sure, especially without looking at the watermarks.
Is it better to leave stamps on their covers? Does anyone know of someone (dealer, etc) in northern California that can help me figure out watermarks without removing or damaging the stamps from the cover material? For instance:

There is a huge difference in value between the 1948 and the 1952 version of the 25pf stamp. Do I need to take this to an expert? I have about 10 of what I think are MiNr 334.

The cancellation is 1953, I believe, but the 5DM stamp must have been printed in 1950, I think. In any case, should these stamps stay on the cover even with the cover being a little thrashed?
Below are a few errors I found as listed in Michel. Do error stamps follow the same catalog/reality rules are regular stamps?

Do blocks of stamps get a premium over the sum of the individual values?

Thanks for all of your insights!