The value of a thing is determined by supply and demand. If you're willing to pay a million dollars for a stamp, that stamp is worth a million dollars. If nobody will pay more than a penny, it's worth a penny. There are some broad guidelines, but we all know that places like
ebay, things often sell for much, much more than they ought to in the heat of the bidding war. Those items aren't necessarily "worth" that much, they just sell that way.
Instead of worrying about what something is worth, decide on your own what a particular stamp is worth to you and don't pay more than that.