That sounds like the 1990 set; the U.S. stamps are listed in the Scott catalogue as ##2508-2511.
The market for first day covers (FDC) is not strong right now. I would check
ebay or bidstart.com, searching for "US 1990 joint issue" or "US 2508" to see if you can match up your covers with existing listings. You will want to make sure you're checking for the same envelope design.
Once you have found something that matches what you have, check completed listings to see what actual selling prices have been. Right now, on bidstart, you can buy a set of all four U.S. stamps from this set on FDCs for a little over $2.00, total.