Check the back side of both stamps. There is probably some green ink off-set, from the sheet these came from, being stacked on top of another sheet before the ink completely dried on that sheet. Any green ink dots, partial lines, partial design, etc. would indicate that these stamps are flat plate printed stamps. The process for rotary printing was such that off-set ink didn't occur but very rarely, and if so, very minutely. #594 was produced by the rotary printing process, so there should be no off-set.
What you have are probably #552s. The one with a straight edge could be a #552a, from a booklet pane. I have several #552's, on and off cover, that measure the same as what you are measuring. Design measurement as well as perforation measurement are not an exact as noted in catalogues and references. They are a close approximation.
Paper production methods and moisture content prior to printing, the printing processes, post printing conditions of storage and I guess other factors can effect and do effect varying degrees of paper shrinkage etc. I've been down this road about size measurements with a couple of the experts and they petty much agree that measurements are not exact and also not complete determining factors regarding any one stamp.
If you feel confident enough that you have a #594, you will need to mail it off to one of the expertizing services to get an expert opinion. As suggested, Bill Weiss will take a look at it for a reasonable fee and advise you if you should pursue a certification further. Sending the stamp by registered mail is as safe as you can go by mail. I definitely use registered mail most of the time. Certified mail is a bit cheaper and probably will work too.
There is a least one conversation regarding possible #594s previously posted on this site. You can search for, find them and read what's been noted before.
Hope this helps some. I'm sure others will have additional information to add to this to help you with you determination.