It's not in the Scott catalogue. It is a revenue stamp. It is listed in the 2009 Edition (this is the most recent) of the Canadian Revenue Stamp Catalogue.
Catalogue no. FB37, it is an 1868 1-cent Bill Stamp from the Third Bill Issue. Value: 60-cents (Canadian).
I seem to recall that I have a clipping somewhere that dealt with some sniggers at court when some saw the queen's portraits on the Australian colonies. It may be where "she was not amused" came from.
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