#1 is strange -- need a closer look. Does not appear to have a number (denomination), though the cancel appears to be a postal usage similar to the others. The cancel in the corner makes one suspect a CTO. Does it have gum?
The stamp in the upper left is the only one I don't recognize. The design is reminiscent of the stamps issued by the Italian state of Parma in 1859. I looked through my catalogue by came up empty.
The rest of the stamps are as Puzzler stated ... German empire ranging from 1923 (300M "Inflation" stamp) to the 1950s East and West Germany. Most are common. The 30pf, Blue "President Heuss" stamp is $4.50 if mint, original gum. The only thing I can tell for sure from the photo is that it's damaged.
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