Thinking back to the 1960s, this area was one of those regional experiments that failed. It was big in the news at that time and for several years and I do know that several stamp issues were made, ostensibly to raise money for the cause.
http://en.wikipedia.org/wiki/BiafraI don't think these achieved any recognized status - certainly not in Scotts - but perhaps they did in Stanley Gibbons or Michel.
Another area with a similar story was Katanga Province but I don't have a set from there to illustrate.
How many other areas with ambitions to independence can be shown? They would, in themselves, make an interesting Topical Collection of mainly Cinderella issues.

