It is Post Card of Kingdom of SERBIA, actually, issued in 1903, Jun 25.
Michel catalog have this set under number 62-71, set of 10 values, overprinted.
Scott is under number 68-75.
Regarding stains as You call it (or rust around), hardly that it is possible to "clean" it. Many samples of this period have same problem, and it is question of paper and glue, which will go damaged by time, and other reasons.
