The early Guatemala stamps on covers are quite rare. I search quite intensively in the auction catalogs all the time. I just don't find them. Guatemala I by Goodman lists those known covers. Here is one I acquired recently, which is inventoried in Guatemala I, as one of 7 recorded covers. This 1876 cover, franked with a 4 Reales stamp (Scott #5), paid a double-rate letter, sent from Guatemala via the Pacific Mail Steamship route to Acapulco, Mexico.
