The stamps with more readable and full cancellations (postmarks) can be worth something to a postmark collector (marcophilatelist) just by themselves.
Some other ones can have varieties in perfs, colours, printing errors to a specialist, etc.
See
http://marcophilie.org/ = France (philatélie et marcophilie)
You could also search under a 600 dpi sscan the Napoleon's or even the sower (Semeuse) stamps for small varieties or have a very interesting collection of them.