Some collect, in addition to postmarks, collect auxiliary markings on cover. These are markings placed by the post office to denote some mail process.
Here is a "Missent" marking in blue. The cover was missent to Charlottesville instead of Clarksville

Here is a cover with two auxiliary markings, a pointing hand, and the notation "Name Duplicated in Directory".

Here is a more contemporary cover with an uncommon marking. $0.20 in postage was added after the original postage was cancelled.

The cleaned up marking:

Cheers,
Antonio