The stationery shown in the images posted by the original poster (OP) was issued May 4, 1991 to cover the 50 kopeck rate for an airmail letter of the 1st weight class (>=20g) abroad. There are two variations of this stationery, the second being without imprinted text on the backflap - a reprint done at the end of 1991.
First a little background story: The postal service of the Soviet Union worked on a dual basis - the postal services of the union republics and the all-union postal service. The first performing the collection and distribution of mail within each of the Soviet republics. The latter performing transport and exchange of mail between union republics and the rest of the World.
The postal service of the Latvian Socialist Soviet Republic independently raised their postage rates for domestic mail as of January 1, 1991. On May 4, 1991, they issued four stationery envelopes with imprinted postage stamps to cover the new postage rates. Three of these were for domestic use (at the time domestic was still considered the USSR) with 15 kopecks as face value. The fourth, the 50 kopeck stationery, was intended for destinations abroad.
There was one hurdle though - at the time of issue of these four stationeries, the all-union postal service only recognized mail franked with Soviet issued postage as being correctly paid. The 15 kopeck stationeries were accepted by and exchanged directly with the Estonian postal service as well as the Lithuanian postal service. All mail abroad had to go via Moscow, but the 50 kopeck stationery was accepted by the Danish postal service via a bilateral agreement between the two postal services - a direct mail exchange via the newly opened flight connection by Scandinavian Air Systems (SAS) between Copenhagen and Riga.
Latvian independence as a sovereign state was officially restored on August 21, 1991, after the failed Soviet coup. Latvian postage stamps were issued again on October 19, 1991, and Latvijas Pasts was again a member of the UPU. As of December 1, 1991, Latvijas Pasts were exchanging mail directly with all countries of the world.
Below the 50 kopeck stationery solo use to Denmark, postmarked July 28, 1991, Riga RPPC (postal centre).
