There is a book for just about everything! In this case, one published by the United Postal Stationery Society in 1989:

It has about 1/3 page on the Placerville imprint, noting it was on a special extra thin tough paper, printed along the left side of the envelope. Value listed only with a dash.
However, as SPQR notes there were all sorts of 1960 souvenir items such as this one I "borrowed" from
ebay:

It would require a closer examination of the paper which might help determine whether yours is from the 1860s or 1960s. The print quality of yours looks quite good. Is it watermarked or have mesh lines in the paper?