Yes - at the time that the collections were assembled.
The Zoellner collection can be viewed by looking at the Siegel Auction catalog, which is still available on the Siegel website:
http://siegelauctions.com/sales.php?sale_no=804You can also download the .pdf or order in print from them.
The Miller collection now lives at the National Postal Museum in the frames in the Gross Gallery. Much of it is online through the Arago website or in the book
Rarity Revealed. See:
http://arago.si.edu/exhibit_238_toc.htmlC.