I have several stamps in my Belgium collection that I could use a little help with. There are six images.

1) judging by the paper remaining on the backs of these stamps I think they are from the same piece. The cancellation is what intrigues me. Is this a special cancellation of some sort?

2) this stamp has what looks like a hole punch. Any ideas on what that might be other than an accidental hole punch?

3) my assumption here is that this is a postage due stamp circa 1960

4) this one really has me stumped. The stamp on the right is the proper olive grey colour. The stamp on the left is a blue grey colour and I can find no reference for the variety. Any ideas?

5) this seems to be cut from a postal stationery card circa 1905. A catalogue reference number would be appreciated.

6) I have several stamps with this fancy cancellation. Is it a pre-cancel type or something else?
Thanks for any help.