The extra overprint on top of the "LOS ANGELES" is called a "dated precancel", in this case from Sears Roebuck Company (SRC) and dated August 1964 (inverted). It is easier to read in the bottom example of the pair.
Here is a similar example from the same series, with the dateline placed where it is supposed to be.

Your 3c stamp may have been used for First Class, or just as likely as a makeup rate in combination with other stamps on a small parcel shipped from Sears.